Toward synthesis of novel C-glycoprotein from human RNase; unexpected stereochemistry of epoxide opening reaction by organolithium reagents in the presence of lewis acid

Shino Manabe, Yukishige Ito, Tomoya Ogawa

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

A nucleophilic attack reaction to 1,2-anhydro-β-D-mannnopyranose by indole derived organolithium reagents in the presence of BF3·OEt2 afforded isomers of C-aryl glycoside corresponds to the basic skeleton of C-linked mannnosyl tryptophan, which is recently identified in human RNase.

Original languageEnglish
Pages (from-to)919-920
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - 1998 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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