Total synthesis of the proposed structure of heronamide C

Kohei Sakanishi, Shunya Itoh, Ryosuke Sugiyama, Shinichi Nishimura, Hideaki Kakeya, Yoshiharu Iwabuchi, Naoki Kanoh

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The total synthesis of the proposed structure of heronamide C was accomplished through a Sato-Micalizio reductive alkyne-alkyne coupling strategy and remote-amine controlled stannylcupration. However, the physical data for the synthetic and natural samples differ from each other, which suggests that the proposed structure should be reinvestigated. The total synthesis of the proposed structure of heronamide C is accomplished by using a Sato-Micalizio reductive alkyne-alkyne coupling strategy and remote-amine-controlled stannylcupration. However, the physical data for the synthetic and natural samples differ from each other, which suggests that the proposed structure should be reinvestigated.

Original languageEnglish
Pages (from-to)1376-1380
Number of pages5
JournalEuropean Journal of Organic Chemistry
Volume2014
Issue number7
DOIs
Publication statusPublished - 2014 Mar 1

Keywords

  • Alkynes
  • Cross-coupling
  • Macrocycles
  • Natural products
  • Total synthesis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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