Total synthesis of broussonetine F: The orthoamide overman rearrangement of an allylic diol

Naoto Hama, Toshihiro Aoki, Shohei Miwa, Miki Yamazaki, Takaaki Sato, Noritaka Chida

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

A first total synthesis of broussonetine F from diethyl l-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.

Original languageEnglish
Pages (from-to)616-619
Number of pages4
JournalOrganic letters
Volume13
Issue number4
DOIs
Publication statusPublished - 2011 Feb 18

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Total synthesis of broussonetine F: The orthoamide overman rearrangement of an allylic diol'. Together they form a unique fingerprint.

Cite this