Topotactic reductive synthesis of A-site cation-ordered perovskite YBaCo2Ox (x = 4.5-5.5) epitaxial thin films

Tsukasa Katayama, Akira Chikamatsu, Tomoteru Fukumura, Tetsuya Hasegawa

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1 Citation (Scopus)

Abstract

A-site cation-ordered perovskite YBaCo2Ox epitaxial films were synthesized by combining pulsed-laser deposition and topotactic reduction using CaH2. The oxygen contents (x) of the films could be controlled in a range of 4.5-5.5 by adjusting the reaction temperature. The c-axis length of the YBaCo2Ox films decreased with decreasing x when x ≥ 5.3 but drastically increased when x ∼ 4.5. In contrast, the in-plane lattice constants remained locked-in by the substrate after the reaction. The metal insulator transition observed in bulk YBaCo2O5.5 was substantially suppressed in the present film, likely because of the epitaxial strain effect. The resistivity of the films was significantly enhanced by changing the x value from ∼ 5.5 to ∼ 4.5, reflecting the distortion of the CoOx layers.

Original languageEnglish
Article number04EJ05
JournalJapanese journal of applied physics
Volume55
Issue number4
DOIs
Publication statusPublished - 2016 Apr

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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