Abstract
(Figure Presented) In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one-dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross-linking (see picture). The main factors that influence this polymerization are the channel size and host framework flexibility.
| Original language | English |
|---|---|
| Pages (from-to) | 4987-4990 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 46 |
| Issue number | 26 |
| DOIs | |
| Publication status | Published - 2007 Jul 18 |
| Externally published | Yes |
Keywords
- Coordination polymers
- Inclusion compounds
- Polymerization
- Radical reactions
- Topochemistry
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Uemura, T., Hiramatsu, D., Kubota, Y., Takata, M., & Kitagawa, S. (2007). Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers. Angewandte Chemie - International Edition, 46(26), 4987-4990. https://doi.org/10.1002/anie.200700242