Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers

Takashi Uemura; Daisuke Hiramatsu; Yoshiki Kubota; Masaki Takata; Susumu Kitagawa

doi:10.1002/anie.200700242

Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers

Takashi Uemura, Daisuke Hiramatsu, Yoshiki Kubota, Masaki Takata, Susumu Kitagawa

Research output: Contribution to journal › Article › peer-review

103 Citations (Scopus)

Abstract

(Figure Presented) In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one-dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross-linking (see picture). The main factors that influence this polymerization are the channel size and host framework flexibility.

Original language	English
Pages (from-to)	4987-4990
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	26
DOIs	https://doi.org/10.1002/anie.200700242
Publication status	Published - 2007 Jul 18
Externally published	Yes

Keywords

Coordination polymers
Inclusion compounds
Polymerization
Radical reactions
Topochemistry

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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title = "Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers",

abstract = "(Figure Presented) In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one-dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross-linking (see picture). The main factors that influence this polymerization are the channel size and host framework flexibility.",

keywords = "Coordination polymers, Inclusion compounds, Polymerization, Radical reactions, Topochemistry",

author = "Takashi Uemura and Daisuke Hiramatsu and Yoshiki Kubota and Masaki Takata and Susumu Kitagawa",

year = "2007",

month = jul,

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doi = "10.1002/anie.200700242",

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T1 - Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers

AU - Uemura, Takashi

AU - Hiramatsu, Daisuke

AU - Kubota, Yoshiki

AU - Takata, Masaki

AU - Kitagawa, Susumu

PY - 2007/7/18

Y1 - 2007/7/18

N2 - (Figure Presented) In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one-dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross-linking (see picture). The main factors that influence this polymerization are the channel size and host framework flexibility.

AB - (Figure Presented) In the groove: Radical polymerization of divinylbenzenes (DVBs) in the one-dimensional nanochannels of porous coordination polymers allows linearly extended topotactic polymerization without cross-linking (see picture). The main factors that influence this polymerization are the channel size and host framework flexibility.

KW - Coordination polymers

KW - Inclusion compounds

KW - Polymerization

KW - Radical reactions

KW - Topochemistry

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DO - 10.1002/anie.200700242

M3 - Article

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JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 26

ER -

Topotactic linear radical polymerization of divinylbenzenes in porous coordination polymers

Abstract

Keywords

ASJC Scopus subject areas

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