Topological variation between hexa- and trithiacalix[6]arene-copper(II) complexes: From sphere to wheel by reducing the number of the sulfur bridges

Noriyoshi Kon, Nobuhiko Iki, Takashi Kajiwara, Tasuku Ito, Sotaro Miyano

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Contrary to hexathiacalix[6]arene (H6L6S) forming [Cu10-(L6S)2]-type spherical decacopper(II) complex, trithiacalix[6]-arene (H6L3S), in which three sulfur bridges of H6L6S are replaced with methyles in an alternate manner, affords nano-sized wheel-shaped octanuclear complex [Cu 8(H2L3S)4] consisting of four [Cu2H2L3S] units.

Original languageEnglish
Pages (from-to)430-431
Number of pages2
JournalChemistry Letters
Volume35
Issue number4
DOIs
Publication statusPublished - 2006 Apr 5

ASJC Scopus subject areas

  • Chemistry(all)

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