Topological modulation of the porous structure of a coordination polymer constructed from a flexible building block via framework-guest interaction during self-assembly

Atsuko Masuya-Suzuki, Nozomi Matsubara, Ryunosuke Karashimada, Hitoshi Hoshino, Nobuhiko Iki

Research output: Contribution to journalArticlepeer-review

Abstract

The porous structure of a coordination polymer constructed from a Sm(iii) ion and a conformationally flexible ligand is modulated by guest solvent molecules. The coordination polymer containing the guest DMF molecule possesses isolated hydrophobic and hydrophilic voids, while the one containing the guest methanol molecule has a microchannel with alternately arranged hydrophobic-hydrophilic surfaces.

Original languageEnglish
Pages (from-to)872-876
Number of pages5
JournalCrystEngComm
Volume18
Issue number6
DOIs
Publication statusPublished - 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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