Three-dimensional structure of large-pore mesoporous cubic Ia3̄d silica with complementary pores and its carbon replica by electron crystallography

Yasuhiro Sakamoto; Tae Wan Kim; Ryong Ryoo; Osamu Terasaki

doi:10.1002/anie.200460449

Three-dimensional structure of large-pore mesoporous cubic Ia3̄d silica with complementary pores and its carbon replica by electron crystallography

Yasuhiro Sakamoto, Tae Wan Kim, Ryong Ryoo, Osamu Terasaki

Research output: Contribution to journal › Article › peer-review

163 Citations (Scopus)

Abstract

A bicontinuous cubic structure was revealed by electron crystallography on a large-pore mesoporous silica with a cubic la3d symmetry synthesized by using a triblock copolymer as a structure-directing agent. Its reconstructed structure (picture, left) is composed of an enantiomeric pair of interwoven three-dimensional mesoporous networks. Ordered complementary pores form interconnections between the two main channel systems at a special flat point of the G-surface (right).

Original language	English
Pages (from-to)	5231-5234
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	39
DOIs	https://doi.org/10.1002/anie.200460449
Publication status	Published - 2004 Oct 4
Externally published	Yes

Keywords

Carbon
Electron crystallography
Mesoporous materials
Silica

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200460449

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Three-dimensional structure of large-pore mesoporous cubic Ia3̄d silica with complementary pores and its carbon replica by electron crystallography. / Sakamoto, Yasuhiro; Kim, Tae Wan; Ryoo, Ryong; Terasaki, Osamu.

In: Angewandte Chemie - International Edition, Vol. 43, No. 39, 04.10.2004, p. 5231-5234.

Research output: Contribution to journal › Article › peer-review

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AU - Terasaki, Osamu

PY - 2004/10/4

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AB - A bicontinuous cubic structure was revealed by electron crystallography on a large-pore mesoporous silica with a cubic la3d symmetry synthesized by using a triblock copolymer as a structure-directing agent. Its reconstructed structure (picture, left) is composed of an enantiomeric pair of interwoven three-dimensional mesoporous networks. Ordered complementary pores form interconnections between the two main channel systems at a special flat point of the G-surface (right).

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KW - Silica

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Three-dimensional structure of large-pore mesoporous cubic Ia3̄d silica with complementary pores and its carbon replica by electron crystallography

Abstract

Keywords

ASJC Scopus subject areas

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