Three-dimensional bicontinuous nanoporous Au/polyaniline hybrid films for high-performance electrochemical supercapacitors

Xingyou Lang; Ling Zhang; Takeshi Fujita; Yi Ding; Mingwei Chen

doi:10.1016/j.jpowsour.2011.09.006

Three-dimensional bicontinuous nanoporous Au/polyaniline hybrid films for high-performance electrochemical supercapacitors

Xingyou Lang, Ling Zhang, Takeshi Fujita, Yi Ding, Mingwei Chen

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

100 Citations (Scopus)

Abstract

We report three-dimensional bicontinuous nanoporous Au/polyaniline (PANI) composite films made by one-step electrochemical polymerization of PANI shell onto dealloyed nanoporous gold (NPG) skeletons for the applications in electrochemical supercapacitors. The NPG/PANI based supercapacitors exhibit ultrahigh volumetric capacitance (∼1500 F cm^-3) and energy density (∼0.078 Wh cm^-3), which are seven and four orders of magnitude higher than these of electrolytic capacitors, with the same power density up to ∼190 W cm^-3. The outstanding capacitive performances result from a novel nanoarchitecture in which pseudocapacitive PANI shells are incorporated into pore channels of highly conductive NPG, making them promising candidates as electrode materials in supercapacitor devices combing high-energy storage densities with high-power delivery.

Original language	English
Pages (from-to)	325-329
Number of pages	5
Journal	Journal of Power Sources
Volume	197
DOIs	https://doi.org/10.1016/j.jpowsour.2011.09.006
Publication status	Published - 2012 Jan 1

Keywords

Capacitors
Hybrid materials
Nanoporous metal
Polyaniline
Supercapacitors

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jpowsour.2011.09.006

Cite this

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title = "Three-dimensional bicontinuous nanoporous Au/polyaniline hybrid films for high-performance electrochemical supercapacitors",

abstract = "We report three-dimensional bicontinuous nanoporous Au/polyaniline (PANI) composite films made by one-step electrochemical polymerization of PANI shell onto dealloyed nanoporous gold (NPG) skeletons for the applications in electrochemical supercapacitors. The NPG/PANI based supercapacitors exhibit ultrahigh volumetric capacitance (∼1500 F cm-3) and energy density (∼0.078 Wh cm-3), which are seven and four orders of magnitude higher than these of electrolytic capacitors, with the same power density up to ∼190 W cm-3. The outstanding capacitive performances result from a novel nanoarchitecture in which pseudocapacitive PANI shells are incorporated into pore channels of highly conductive NPG, making them promising candidates as electrode materials in supercapacitor devices combing high-energy storage densities with high-power delivery.",

keywords = "Capacitors, Hybrid materials, Nanoporous metal, Polyaniline, Supercapacitors",

author = "Xingyou Lang and Ling Zhang and Takeshi Fujita and Yi Ding and Mingwei Chen",

note = "Funding Information: This work was sponsored by Global COE for Materials Research and Education, the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan, and Program for New Century Excellent Talents in University, the Ministry of Education, China. ",

year = "2012",

month = jan,

day = "1",

doi = "10.1016/j.jpowsour.2011.09.006",

language = "English",

volume = "197",

pages = "325--329",

journal = "Journal of Power Sources",

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T1 - Three-dimensional bicontinuous nanoporous Au/polyaniline hybrid films for high-performance electrochemical supercapacitors

AU - Lang, Xingyou

AU - Zhang, Ling

AU - Fujita, Takeshi

AU - Ding, Yi

AU - Chen, Mingwei

N1 - Funding Information: This work was sponsored by Global COE for Materials Research and Education, the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan, and Program for New Century Excellent Talents in University, the Ministry of Education, China.

PY - 2012/1/1

Y1 - 2012/1/1

N2 - We report three-dimensional bicontinuous nanoporous Au/polyaniline (PANI) composite films made by one-step electrochemical polymerization of PANI shell onto dealloyed nanoporous gold (NPG) skeletons for the applications in electrochemical supercapacitors. The NPG/PANI based supercapacitors exhibit ultrahigh volumetric capacitance (∼1500 F cm-3) and energy density (∼0.078 Wh cm-3), which are seven and four orders of magnitude higher than these of electrolytic capacitors, with the same power density up to ∼190 W cm-3. The outstanding capacitive performances result from a novel nanoarchitecture in which pseudocapacitive PANI shells are incorporated into pore channels of highly conductive NPG, making them promising candidates as electrode materials in supercapacitor devices combing high-energy storage densities with high-power delivery.

AB - We report three-dimensional bicontinuous nanoporous Au/polyaniline (PANI) composite films made by one-step electrochemical polymerization of PANI shell onto dealloyed nanoporous gold (NPG) skeletons for the applications in electrochemical supercapacitors. The NPG/PANI based supercapacitors exhibit ultrahigh volumetric capacitance (∼1500 F cm-3) and energy density (∼0.078 Wh cm-3), which are seven and four orders of magnitude higher than these of electrolytic capacitors, with the same power density up to ∼190 W cm-3. The outstanding capacitive performances result from a novel nanoarchitecture in which pseudocapacitive PANI shells are incorporated into pore channels of highly conductive NPG, making them promising candidates as electrode materials in supercapacitor devices combing high-energy storage densities with high-power delivery.

KW - Capacitors

KW - Hybrid materials

KW - Nanoporous metal

KW - Polyaniline

KW - Supercapacitors

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DO - 10.1016/j.jpowsour.2011.09.006

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EP - 329

JO - Journal of Power Sources

JF - Journal of Power Sources

SN - 0378-7753

ER -

Three-dimensional bicontinuous nanoporous Au/polyaniline hybrid films for high-performance electrochemical supercapacitors

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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