Third-order electric susceptibilities of halogen-bridged mixed-valence pt complexes: [pt(en)2][pt(en)2x2](c104)4, x = c1, br, i, en=ethylenediamine

Yoshiki Wada; Masahiro Yamashita

doi:10.1143/JJAP.29.2744

Third-order electric susceptibilities of halogen-bridged mixed-valence pt complexes: [pt(en)₂][pt(en)₂x₂](c10₄)₄, x = c1, br, i, en=ethylenediamine

Yoshiki Wada, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Third-order electric susceptibilitiesX³_zzz(-3w,w,w,w)of the halogen-bridged mixed-valence Pt complexes, [Pt(en)₂][Pt(en)₂X₂](C10₄)₄, (X = C1, Br, I) are calculated using a three level model, taking account of the ground state and odd and even charge-transfer excitons. The values obtained are in the range of 10-¹²-10^-8 esu and are comparable to, or slightly larger than those observed in polydiacetylenes

Original language	English
Pages (from-to)	2744-2745
Number of pages	2
Journal	Japanese journal of applied physics
Volume	29
Issue number	12R
DOIs	https://doi.org/10.1143/JJAP.29.2744
Publication status	Published - 1990 Dec
Externally published	Yes

Keywords

Charge transfer exciton
Halogen-bridged mixed-valence Pt complexes
One-dimensional electron system
Optical nonlinearity
Oscillator strength
Third-order electric susceptibilities
Three-level model

ASJC Scopus subject areas

Engineering(all)
Physics and Astronomy(all)

Access to Document

10.1143/JJAP.29.2744

Cite this

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title = "Third-order electric susceptibilities of halogen-bridged mixed-valence pt complexes: [pt(en)2][pt(en)2x2](c104)4, x = c1, br, i, en=ethylenediamine",

abstract = "Third-order electric susceptibilitiesX3zzz(-3w,w,w,w)of the halogen-bridged mixed-valence Pt complexes, [Pt(en)2][Pt(en)2X2](C104)4, (X = C1, Br, I) are calculated using a three level model, taking account of the ground state and odd and even charge-transfer excitons. The values obtained are in the range of 10-12-10-8 esu and are comparable to, or slightly larger than those observed in polydiacetylenes",

keywords = "Charge transfer exciton, Halogen-bridged mixed-valence Pt complexes, One-dimensional electron system, Optical nonlinearity, Oscillator strength, Third-order electric susceptibilities, Three-level model",

author = "Yoshiki Wada and Masahiro Yamashita",

year = "1990",

month = dec,

doi = "10.1143/JJAP.29.2744",

language = "English",

volume = "29",

pages = "2744--2745",

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T1 - Third-order electric susceptibilities of halogen-bridged mixed-valence pt complexes

T2 - [pt(en)2][pt(en)2x2](c104)4, x = c1, br, i, en=ethylenediamine

AU - Wada, Yoshiki

AU - Yamashita, Masahiro

PY - 1990/12

Y1 - 1990/12

N2 - Third-order electric susceptibilitiesX3zzz(-3w,w,w,w)of the halogen-bridged mixed-valence Pt complexes, [Pt(en)2][Pt(en)2X2](C104)4, (X = C1, Br, I) are calculated using a three level model, taking account of the ground state and odd and even charge-transfer excitons. The values obtained are in the range of 10-12-10-8 esu and are comparable to, or slightly larger than those observed in polydiacetylenes

AB - Third-order electric susceptibilitiesX3zzz(-3w,w,w,w)of the halogen-bridged mixed-valence Pt complexes, [Pt(en)2][Pt(en)2X2](C104)4, (X = C1, Br, I) are calculated using a three level model, taking account of the ground state and odd and even charge-transfer excitons. The values obtained are in the range of 10-12-10-8 esu and are comparable to, or slightly larger than those observed in polydiacetylenes

KW - Charge transfer exciton

KW - Halogen-bridged mixed-valence Pt complexes

KW - One-dimensional electron system

KW - Optical nonlinearity

KW - Oscillator strength

KW - Third-order electric susceptibilities

KW - Three-level model

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