Thiophene-based chiral small bandgap π-conjugated polymers: Synthesis and optical properties

Aohan Wang, Kohsuke Kawabata, Hiromasa Goto

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A series of thiophene-based chiral small bandgap π-conjugated polymers was successfully synthesized. Optical properties of the polymers were investigated by using UV-vis, photoluminescence (PL), circular dichroism (CD) spectroscopies, and specific rotation measurements. Especially, the isothianaphthene-thiophene based copolymers display 10-20 nm longer absorption maximum than those of thiophene-thiophene copolymers in the UV-vis. PL measurements demonstrate that the polymer exhibit light emission. CD spectroscopy measurements reveal helical π-stacking structure of the polymers.

Original languageEnglish
Pages (from-to)360-366
Number of pages7
JournalDesigned Monomers and Polymers
Volume18
Issue number4
DOIs
Publication statusPublished - 2015 May 19
Externally publishedYes

Keywords

  • chiral
  • isothianaphthene
  • polycondensation
  • π-stacking

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

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