Thieme Chemistry Journals Awardees - Where Are They Now? Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Ethers Using Heteroaryl Exchange Reaction

Saori Tanii, Mieko Arisawa, Takaya Tougo, Kiyofumi Horiuchi, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

Unsymmetric di(heteroaryl) ethers were synthesized by the rhodium-catalyzed heteroaryl exchange reaction of heteroaryl aryl ethers and heteroaryl esters at equilibrium. Diverse unsymmetric di(heteroaryl) ethers containing five- and six-membered heteroarenes were obtained. Di(heteroaryl) ethers can be synthesized starting from diaryl ethers, because heteroaryl aryl ethers are obtained by the heteroaryl exchange reaction of diaryl ethers.

Original languageEnglish
Pages (from-to)1601-1607
Number of pages7
JournalSynlett
Volume28
Issue number13
DOIs
Publication statusPublished - 2017 Aug 14

Keywords

  • C-O bond cleavage
  • heteroaryl benzoates
  • heteroaryl exchange reaction
  • rhodium
  • unsymmetric di(heteroaryl) ethers

ASJC Scopus subject areas

  • Organic Chemistry

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