Thermodynamic properties of different titanium ions in fused LiCl-KCl eutectic

Jianxun Song; Qiuyu Wang; Xiaobo Zhu; Jungang Hou; Shuqiang Jiao; Hongmin Zhu

doi:10.1002/9781118888551.ch25

Thermodynamic properties of different titanium ions in fused LiCl-KCl eutectic

Jianxun Song, Qiuyu Wang, Xiaobo Zhu, Jungang Hou, Shuqiang Jiao, Hongmin Zhu

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Citations (Scopus)

Abstract

This work presents the results of a study on the Ti³⁺/Ti ²⁺ couple redox potentials vs. Cl^-/Cl₂ at the temperature range (673 to 1073 K) in fused LiCl-KCl eutectic by direct Potentiometric method. Initial concentrations of TiCl_x in solvents did not exceed 5.0 mol%. Basic thermodynamic properties of the reactions TiCl₂+1/2Cl₂(g)=TiCl₃ were calculated using the temperature dependencies of apparent standard potentials of the couples E ^•_Ti³⁺/Ti²⁺.

Original language	English
Title of host publication	Rare Metal Technology 2014 - Held During TMS 2014 143rd Annual Meeting and Exhibition
Publisher	Minerals, Metals and Materials Society
Pages	133-138
Number of pages	6
ISBN (Print)	9781118888827
DOIs	https://doi.org/10.1002/9781118888551.ch25
Publication status	Published - 2014 Jan 1
Externally published	Yes
Event	Rare Metal Technology 2014 - TMS 2014 143rd Annual Meeting and Exhibition - San Diego, CA, United States Duration: 2014 Feb 16 → 2014 Feb 20

Publication series

Name	TMS Annual Meeting

Other

Other	Rare Metal Technology 2014 - TMS 2014 143rd Annual Meeting and Exhibition
Country	United States
City	San Diego, CA
Period	14/2/16 → 14/2/20

Keywords

Molten salts
Redox potentials
Thermodynamics
Titanium chlorides

ASJC Scopus subject areas

Condensed Matter Physics
Mechanics of Materials
Metals and Alloys

Access to Document

10.1002/9781118888551.ch25

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Cite this

Thermodynamic properties of different titanium ions in fused LiCl-KCl eutectic. / Song, Jianxun; Wang, Qiuyu; Zhu, Xiaobo; Hou, Jungang; Jiao, Shuqiang; Zhu, Hongmin.

Rare Metal Technology 2014 - Held During TMS 2014 143rd Annual Meeting and Exhibition. Minerals, Metals and Materials Society, 2014. p. 133-138 (TMS Annual Meeting).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Song, J, Wang, Q, Zhu, X, Hou, J, Jiao, S & Zhu, H 2014, Thermodynamic properties of different titanium ions in fused LiCl-KCl eutectic. in Rare Metal Technology 2014 - Held During TMS 2014 143rd Annual Meeting and Exhibition. TMS Annual Meeting, Minerals, Metals and Materials Society, pp. 133-138, Rare Metal Technology 2014 - TMS 2014 143rd Annual Meeting and Exhibition, San Diego, CA, United States, 14/2/16. https://doi.org/10.1002/9781118888551.ch25

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title = "Thermodynamic properties of different titanium ions in fused LiCl-KCl eutectic",

abstract = "This work presents the results of a study on the Ti3+/Ti 2+ couple redox potentials vs. Cl-/Cl2 at the temperature range (673 to 1073 K) in fused LiCl-KCl eutectic by direct Potentiometric method. Initial concentrations of TiClx in solvents did not exceed 5.0 mol%. Basic thermodynamic properties of the reactions TiCl2+1/2Cl2(g)=TiCl3 were calculated using the temperature dependencies of apparent standard potentials of the couples E •Ti3+/Ti2+.",

keywords = "Molten salts, Redox potentials, Thermodynamics, Titanium chlorides",

author = "Jianxun Song and Qiuyu Wang and Xiaobo Zhu and Jungang Hou and Shuqiang Jiao and Hongmin Zhu",

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AU - Jiao, Shuqiang

AU - Zhu, Hongmin

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AB - This work presents the results of a study on the Ti3+/Ti 2+ couple redox potentials vs. Cl-/Cl2 at the temperature range (673 to 1073 K) in fused LiCl-KCl eutectic by direct Potentiometric method. Initial concentrations of TiClx in solvents did not exceed 5.0 mol%. Basic thermodynamic properties of the reactions TiCl2+1/2Cl2(g)=TiCl3 were calculated using the temperature dependencies of apparent standard potentials of the couples E •Ti3+/Ti2+.

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KW - Redox potentials

KW - Thermodynamics

KW - Titanium chlorides

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