Thermodynamic properties of different titanium ions in fused LiCl-KCl eutectic

Jianxun Song, Qiuyu Wang, Xiaobo Zhu, Jungang Hou, Shuqiang Jiao, Hongmin Zhu

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

This work presents the results of a study on the Ti3+/Ti 2+ couple redox potentials vs. Cl-/Cl2 at the temperature range (673 to 1073 K) in fused LiCl-KCl eutectic by direct Potentiometric method. Initial concentrations of TiClx in solvents did not exceed 5.0 mol%. Basic thermodynamic properties of the reactions TiCl2+1/2Cl2(g)=TiCl3 were calculated using the temperature dependencies of apparent standard potentials of the couples E Ti3+/Ti2+.

Original languageEnglish
Title of host publicationRare Metal Technology 2014 - Held During TMS 2014 143rd Annual Meeting and Exhibition
PublisherMinerals, Metals and Materials Society
Pages133-138
Number of pages6
ISBN (Print)9781118888827
DOIs
Publication statusPublished - 2014 Jan 1
Externally publishedYes
EventRare Metal Technology 2014 - TMS 2014 143rd Annual Meeting and Exhibition - San Diego, CA, United States
Duration: 2014 Feb 162014 Feb 20

Publication series

NameTMS Annual Meeting

Other

OtherRare Metal Technology 2014 - TMS 2014 143rd Annual Meeting and Exhibition
CountryUnited States
CitySan Diego, CA
Period14/2/1614/2/20

Keywords

  • Molten salts
  • Redox potentials
  • Thermodynamics
  • Titanium chlorides

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys

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