KCl-KF-AlCl3-AlF3 系の熱力学的解析

Translated title of the contribution: Thermodynamic analysis of KCl-KF-AlCl3-AlF3 system

Research output: Contribution to journalArticlepeer-review


Phase diagrams and thermodynamic properties of KCl-KF, KCl-AlCl3, KF-AlF3, KCl-KF-AlF3 systems have been analyzed based on the experimental data. The Gibbs energies of the liquid and halite phases were approximated with the two-sublattice model for ionic liquid and crystal, respectively. The Gibbs energies of other phases were approximated by the line compound model. Most of the experimental information could be reproduced by the present set of thermodynamic parameters. This set of parameters can be predicted from the phase equilibria and thermodynamic properties at full range of composition in KCl-KF-AlF3 system.

Translated title of the contributionThermodynamic analysis of KCl-KF-AlCl3-AlF3 system
Original languageJapanese
Pages (from-to)32-38
Number of pages7
JournalKeikinzoku/Journal of Japan Institute of Light Metals
Issue number1
Publication statusPublished - 2021 Jan 15

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry


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