Abstract
A cyanide-bridged molecular square, [Co2Fe2(CN) 6(tp*)2- (dtbbpy)4](PF6) 2·2MeOH (1) (tp* = hydrotris(3,5-dimethylpyrazol-1-yl) borate and dtbbpy = 4,4′-di-tert-butyl-2,2′-bipyridine) was prepared by the reaction of (Bu4N)[Fe(CN)3(tp*)] with Co(CF3SO3)2·6H2O and dtbbpy in methanol. Variable temperature X-ray structural analyses, magnetic and spectroscopic data revealed that 1 exhibited novel thermal two-stepped spin transitions induced by intramolecular electron transfers.
| Original language | English |
|---|---|
| Pages (from-to) | 978-979 |
| Number of pages | 2 |
| Journal | Chemistry Letters |
| Volume | 39 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 2010 Sep 6 |
| Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)
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Cite this
Nihei, M., Sekine, Y., Suganami, N., & Oshio, H. (2010). Thermally two-stepped spin transitions induced by intramolecular electron transfers in a cyanide-bridged molecular square. Chemistry Letters, 39(9), 978-979. https://doi.org/10.1246/cl.2010.978