Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

Original languageEnglish
Pages (from-to)69-70
Number of pages2
JournalChemistry Letters
Issue number1
DOIs
Publication statusPublished - 1998 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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