Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

Masaaki Okazaki; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.1998.69

Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Thermolysis of L_nIr(C₂H₅)(H) [L_n = {η²-Me₂Si(CH₂)₂PPh ₂}-(PMe₃)₂] led to the clean formation of a 1:1 mixture of ethene complex L_nIr(C₂H₄) and dihydrido complex L_nIr(H)₂. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

Original language	English
Pages (from-to)	69-70
Number of pages	2
Journal	Chemistry Letters
Issue number	1
DOIs	https://doi.org/10.1246/cl.1998.69
Publication status	Published - 1998

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Chemistry(all)

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title = "Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-",

abstract = "Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.",

author = "Masaaki Okazaki and Hiromi Tobita and Hiroshi Ogino",

year = "1998",

doi = "10.1246/cl.1998.69",

language = "English",

pages = "69--70",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

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T1 - Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

AU - Okazaki, Masaaki

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1998

Y1 - 1998

N2 - Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

AB - Thermolysis of LnIr(C2H5)(H) [Ln = {η2-Me2Si(CH2)2PPh 2}-(PMe3)2] led to the clean formation of a 1:1 mixture of ethene complex LnIr(C2H4) and dihydrido complex LnIr(H)2. The former product is proved to be an efficient precursor of an unsaturated silyliridium(I) species through dissociation of ethene.

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DO - 10.1246/cl.1998.69

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JF - Chemistry Letters

IS - 1

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Thermal reaction of ethyl(hydrido){(2-phosphinoethyl)silyl}iridium(III) complex -formation of a {(2-phosphinoethyl)silyl}(ethene)iridium(I) complex-

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