Thermal equilibrium between a lattice-framework disilene and the corresponding silylene

Shinobu Tsutsui, Hiromasa Tanaka, Eunsang Kwon, Shigeki Matsumoto, Kenkichi Sakamoto

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

The existence of the thermal equilibrium between 2,3,4,6,7,8,2′, 3′,4′, &, 7′,8′-dodeca-tert-butyl[5,5′]-bi{1, 5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2′, 7′-tetraene and the corresponding silylene was revealed by trapping experiments. The equilibrium was investigated by DFT calculations.

Original languageEnglish
Pages (from-to)5659-5661
Number of pages3
JournalOrganometallics
Volume23
Issue number24
DOIs
Publication statusPublished - 2004 Nov 22
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Thermal equilibrium between a lattice-framework disilene and the corresponding silylene'. Together they form a unique fingerprint.

Cite this