Theoretical study on stereochemical diversity in the addition of water to disilene

Masae Takahashi; Tamás Veszprémi; Balazs Hajgató; Mitsuo Kira

doi:10.1021/om000385u

Theoretical study on stereochemical diversity in the addition of water to disilene

Masae Takahashi, Tamás Veszprémi, Balazs Hajgató, Mitsuo Kira

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

An ab initio MO study of the mechanisms for the addition of water to disilene (H₂Si double bond SiH₂) has shown that two bimolecular addition pathways are feasible: one proceeds in a syn-addition manner, while the other proceeds in an anti-addition manner. In the latter pathway, the intracomplex electrophilic attack of a water hydrogen in an initial weak nucleophilic complex between disilene and water occurs with the antarafacial approach according to the Woodward-Hoffmann rules.

Original language	English
Pages (from-to)	4660-4662
Number of pages	3
Journal	Organometallics
Volume	19
Issue number	23
DOIs	https://doi.org/10.1021/om000385u
Publication status	Published - 2000 Nov 1
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om000385u

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AU - Hajgató, Balazs

AU - Kira, Mitsuo

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Theoretical study on stereochemical diversity in the addition of water to disilene

Abstract

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