The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6]

Hitoshi Miyasaka, Naohide Matsumoto, Hisashi Ōkawa, Nazzareno Re, Emma Gallo, Carlo Floriani

Research output: Contribution to journalArticlepeer-review

140 Citations (Scopus)

Abstract

Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers. (Figure Presented.)

Original languageEnglish
Pages (from-to)1446-1448
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume34
Issue number13-14
DOIs
Publication statusPublished - 1995 Jul 31
Externally publishedYes

Keywords

  • Prussian blue
  • magnetic properties
  • manganese compounds
  • salen complexes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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