TY - JOUR
T1 - The temperature dependence of strengthening mechanisms in Ni-based superalloys
T2 - A newly re-defined cuboidal model and its implications for strength design
AU - Wu, Liberty
AU - Osada, Toshio
AU - Yokokawa, Tadaharu
AU - Chang, Yaling
AU - Kawagishi, Kyoko
N1 - Funding Information:
This research was supported mainly by the Council for Science, Technology and Innovation ( CSTI ), Cross-ministerial Strategic Innovation Promotion Program ( SIP ), “Structural Materials for Innovation” (Unit No. B21), and by the “Materials Integration” program for the Revolutionary Design System of Structural Materials (Funding Agency: JST ). We acknowledge Dr. Hiroshi Harada for his advice on the research and Dr. Toshiharu Kobayashi and Dr. Makoto Osawa for their experimental assistance and technical guidance, respectively. We also thank Ms. Yuka Hara and Mr. Masahiko Kawasaki for their assistance with electron microscopic analysis and glass-sealed sample preparations. We would like to thank Editage (www.editage.jp) for English language editing.
Publisher Copyright:
© 2022 Elsevier B.V.
PY - 2023/1/10
Y1 - 2023/1/10
N2 - The development of advanced Ni-based superalloys for gas turbine applications is strongly reliant on alloy strength design and optimisation through microstructure control. Herein, a new model for precipitation strengthening in Ni-based superalloys with large amounts of cuboidal γ’ particles has been further developed from a previous work with re-defined physical parameters, allowing for a smooth integration of weak and strong pair-coupling models. The predicted results were directly validated using commercial alloy (Alloy720Li)-based single-crystal tie-line model alloys with specially designed γ’ particle sizes and volume fractions, which made it possible to extract the temperature dependence of all factors responsible for the overall strength, such as the γ/γ’ mixture, particle strengthening, and solid-solution strengthening. The physical parameters controlling the strength increment in particle strengthening were thoroughly examined as well. The proposed pair-coupling model with the assumption of cuboidal γ’ particles accurately predicts alloy strength over a wide temperature range (up to 760 °C) for volume fractions > 45%, whereas the classical model that assumes the presence of spherical γ’ particles is valid only for volume fractions < 20%. More importantly, our finding suggests that the cuboidal γ’, with its stronger dependence of strengthening on volume fractions than on size and higher strength increment with increasing APB energy, can allow easier strength optimization of turbine discs over spherical γ’.
AB - The development of advanced Ni-based superalloys for gas turbine applications is strongly reliant on alloy strength design and optimisation through microstructure control. Herein, a new model for precipitation strengthening in Ni-based superalloys with large amounts of cuboidal γ’ particles has been further developed from a previous work with re-defined physical parameters, allowing for a smooth integration of weak and strong pair-coupling models. The predicted results were directly validated using commercial alloy (Alloy720Li)-based single-crystal tie-line model alloys with specially designed γ’ particle sizes and volume fractions, which made it possible to extract the temperature dependence of all factors responsible for the overall strength, such as the γ/γ’ mixture, particle strengthening, and solid-solution strengthening. The physical parameters controlling the strength increment in particle strengthening were thoroughly examined as well. The proposed pair-coupling model with the assumption of cuboidal γ’ particles accurately predicts alloy strength over a wide temperature range (up to 760 °C) for volume fractions > 45%, whereas the classical model that assumes the presence of spherical γ’ particles is valid only for volume fractions < 20%. More importantly, our finding suggests that the cuboidal γ’, with its stronger dependence of strengthening on volume fractions than on size and higher strength increment with increasing APB energy, can allow easier strength optimization of turbine discs over spherical γ’.
KW - Deformation
KW - High temperature
KW - Ni-based superalloy
KW - Precipitation strengthening
KW - Thermal treatment
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U2 - 10.1016/j.jallcom.2022.167508
DO - 10.1016/j.jallcom.2022.167508
M3 - Article
AN - SCOPUS:85139852651
SN - 0925-8388
VL - 931
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
M1 - 167508
ER -