The synergistic effect of nanoporous aupd alloy catalysts on highly chemoselective 1,4-hydrosilylation of conjugated cyclic enones

Qiang Chen, Shinya Tanaka, Takeshi Fujita, Luyang Chen, Taketoshi Minato, Yoshifumi Ishikawa, Mingwei Chen, Naoki Asao, Yoshinori Yamamoto, Tienan Jin

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-hydrosilylation of the conjugated cyclic enones with hydrosilane in comparison with the monometallic nanoporous Au and Pd catalysts. The enhanced catalytic properties of AuPdNPore arise mainly from the nanoporous structure and the synergistic effect of the AuPd alloy.

Original languageEnglish
Pages (from-to)3344-3346
Number of pages3
JournalChemical Communications
Volume50
Issue number25
DOIs
Publication statusPublished - 2014 Feb 27

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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