The stability of anhydrous phase B, Mg14Si5O24, at mantle transition zone conditions

Liang Yuan, Eiji Ohtani, Yuki Shibazaki, Shin Ozawa, Zhenmin Jin, Akio Suzuki, Daniel J. Frost

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)


The stability of anhydrous phase B, Mg14Si5O24, has been determined in the pressure range of 14–21 GPa and the temperature range of 1100–1700 °C with both normal and reversal experiments using multi-anvil apparatus. Our results demonstrate that anhydrous phase B is stable at pressure–temperature conditions corresponding to the shallow depth region of the mantle’s transition zone and it decomposes into periclase and wadsleyite at greater depths. The decomposition boundary of anhydrous phase B into wadsleyite and periclase has a positive phase transition slope and can be expressed by the following equation: P(GPa) = 7.5 + 6.6 × 10−3T (°C). This result is consistent with a recent result on the decomposition boundary of anhydrous phase B (Kojitani et al., Am Miner 102:2032–2044, 2017). However, our phase boundary deviates significantly from this previous study at temperatures < 1400 °C. Subducting carbonates may be reduced at depths > 250 km, which could contribute ferropericlase (Mg, Fe)O or magnesiowustite (Fe, Mg)O into the deep mantle. Incongruent melting of hydrous peridotite may also produce MgO-rich compounds. Anh-B could form in these conditions due to reactions between Mg-rich oxides and silicates. Anh-B might provide a new interpretation for the origin of diamonds containing ferropericlase–olivine inclusions and chromitites which have been found to have ultrahigh-pressure characteristics. We propose that directly touching ferropericlase–olivine inclusions found in natural diamonds might be the retrogressive products of anhydrous phase B decomposing via the reaction (Mg,Fe)14Si5O24 (Anh-B) = (Mg,Fe)2SiO4 (olivine) + (Mg,Fe)O (periclase). This decomposition may occur during the transportation of the host diamonds from their formation depths of < 500 km in the upper part of the mantle transition zone to the surface.

Original languageEnglish
Pages (from-to)523-531
Number of pages9
JournalPhysics and Chemistry of Minerals
Issue number6
Publication statusPublished - 2018 Jun 1
Externally publishedYes


  • Anhydrous phase B
  • Diamond inclusions
  • High-P chromite
  • Phase transition
  • Raman spectroscopy

ASJC Scopus subject areas

  • Materials Science(all)
  • Geochemistry and Petrology


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