The reaction of organozinc compounds with an aldehyde within a crystalline molecular flask

Koki Ikemoto, Yasuhide Inokuma, Makoto Fujita

    Research output: Contribution to journalArticlepeer-review

    35 Citations (Scopus)

    Abstract

    (Figure Presented) Organozinc addition reactions were carried out on an aldehyde within a porous coordination network (see picture) in a single-crystal-to-single-crystal fashion, and the product structure was unambiguously determined by X-ray diffraction. Moreover, a one-pot two-step reaction in a single crystal furnished an ester from an aldehyde without the network losing crystallinity.

    Original languageEnglish
    Pages (from-to)5750-5752
    Number of pages3
    JournalAngewandte Chemie - International Edition
    Volume49
    Issue number33
    DOIs
    Publication statusPublished - 2010 Aug 2

    Keywords

    • Metal-organic frameworks
    • Organozinc compounds
    • Porous networks
    • Single-crystal modifications
    • X-ray diffraction

    ASJC Scopus subject areas

    • Catalysis
    • Chemistry(all)

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