The MCD spectroscopy of corrolazines and triazatetrabenzocorroles

John Mack, Masaru Bunya, David Lansky, David P. Goldberg, Nagao Kobayashi

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

We report the first MCD spectral data for free base corrolazine and a transition metal corrolazine complex. A detailed analysis of the MCD and UV-visible absorption spectroscopy of these compounds and phosphorous corrolazine and triazatetrabenzocorroles is carried out based on the results of TD-DFT calculations and an application of Michl's perimeter model.

Original languageEnglish
Pages (from-to)1369-1380
Number of pages12
JournalHeterocycles
Volume76
Issue number2
DOIs
Publication statusPublished - 2008 Nov 1

Keywords

  • Corrolazine
  • MCD
  • Porphyrinoid
  • TD-DPT
  • Tetrabenzocorrolazine

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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