The magnetic anisotropy and assembling of the lanthanide coordination units in [Fe(bpca)2][Er(NO3)3(H2O)4]NO3

Marilena Ferbinteanu; Takashi Kajiwara; Fanica Cimpoesu; Kensuke Katagiri; Masahiro Yamashita

doi:10.1016/j.poly.2006.10.003

The magnetic anisotropy and assembling of the lanthanide coordination units in [Fe(bpca)₂][Er(NO₃)₃(H₂O)₄]NO₃

Marilena Ferbinteanu, Takashi Kajiwara, Fanica Cimpoesu, Kensuke Katagiri, Masahiro Yamashita

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The magnetic properties of the title compound are discussed in correlation with the molecular and crystal structure. The bimetallic complex [Fe(bpca)₂][Er(NO₃)₃(H₂O)₄](NO₃) (where Hbpca = bis(2-pyridilcarbonyl)amine) crystallizes in the triclinic space group P over(1, ̄) exhibiting stacks of [Fe(bpca)₂]⁺ and [Er(NO₃)₃(H₂O)₄] entities connected by hydrogen bonds. The [Er(NO₃)₃(H₂O)₄] units are connected by hydrogen bonds established between coordinated aqua and nitrate ligands. Static and dynamic magnetic properties are reported. The complex exhibits the magnetization lag in ac magnetic field of 10-1400 Hz, above 1.8 K, under a static magnetic field. The ab initio calculations, including ligand field and spin orbit effects illuminated the anisotropy properties of the lanthanide ions in the complex, revealing the orientation and extension of the lobes corresponding to the easy magnetization axes.

Original language	English
Pages (from-to)	2069-2073
Number of pages	5
Journal	Polyhedron
Volume	26
Issue number	9-11
DOIs	https://doi.org/10.1016/j.poly.2006.10.003
Publication status	Published - 2007 Jun 15

Keywords

Ab initio
Hydrogen bond
Lanthanide
Magnetic anisotropy
Magnetic properties

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.poly.2006.10.003

Cite this

@article{79341ae67dd34b50b72312d55bd6a0e2,

title = "The magnetic anisotropy and assembling of the lanthanide coordination units in [Fe(bpca)2][Er(NO3)3(H2O)4]NO3",

abstract = "The magnetic properties of the title compound are discussed in correlation with the molecular and crystal structure. The bimetallic complex [Fe(bpca)2][Er(NO3)3(H2O)4](NO3) (where Hbpca = bis(2-pyridilcarbonyl)amine) crystallizes in the triclinic space group P over(1,{\= }) exhibiting stacks of [Fe(bpca)2]+ and [Er(NO3)3(H2O)4] entities connected by hydrogen bonds. The [Er(NO3)3(H2O)4] units are connected by hydrogen bonds established between coordinated aqua and nitrate ligands. Static and dynamic magnetic properties are reported. The complex exhibits the magnetization lag in ac magnetic field of 10-1400 Hz, above 1.8 K, under a static magnetic field. The ab initio calculations, including ligand field and spin orbit effects illuminated the anisotropy properties of the lanthanide ions in the complex, revealing the orientation and extension of the lobes corresponding to the easy magnetization axes.",

keywords = "Ab initio, Hydrogen bond, Lanthanide, Magnetic anisotropy, Magnetic properties",

author = "Marilena Ferbinteanu and Takashi Kajiwara and Fanica Cimpoesu and Kensuke Katagiri and Masahiro Yamashita",

note = "Funding Information: This work was supported by Japan Society for Promotion Science post-doctoral fellowship program (P04390-MF) and COE program (F.C.). M.F. and F.C. also thank to CNCSIS/RO (886 and 1422/2005). Copyright: Copyright 2007 Elsevier B.V., All rights reserved.",

year = "2007",

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doi = "10.1016/j.poly.2006.10.003",

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T1 - The magnetic anisotropy and assembling of the lanthanide coordination units in [Fe(bpca)2][Er(NO3)3(H2O)4]NO3

AU - Ferbinteanu, Marilena

AU - Kajiwara, Takashi

AU - Cimpoesu, Fanica

AU - Katagiri, Kensuke

AU - Yamashita, Masahiro

N1 - Funding Information: This work was supported by Japan Society for Promotion Science post-doctoral fellowship program (P04390-MF) and COE program (F.C.). M.F. and F.C. also thank to CNCSIS/RO (886 and 1422/2005). Copyright: Copyright 2007 Elsevier B.V., All rights reserved.

PY - 2007/6/15

Y1 - 2007/6/15

N2 - The magnetic properties of the title compound are discussed in correlation with the molecular and crystal structure. The bimetallic complex [Fe(bpca)2][Er(NO3)3(H2O)4](NO3) (where Hbpca = bis(2-pyridilcarbonyl)amine) crystallizes in the triclinic space group P over(1, ̄) exhibiting stacks of [Fe(bpca)2]+ and [Er(NO3)3(H2O)4] entities connected by hydrogen bonds. The [Er(NO3)3(H2O)4] units are connected by hydrogen bonds established between coordinated aqua and nitrate ligands. Static and dynamic magnetic properties are reported. The complex exhibits the magnetization lag in ac magnetic field of 10-1400 Hz, above 1.8 K, under a static magnetic field. The ab initio calculations, including ligand field and spin orbit effects illuminated the anisotropy properties of the lanthanide ions in the complex, revealing the orientation and extension of the lobes corresponding to the easy magnetization axes.

AB - The magnetic properties of the title compound are discussed in correlation with the molecular and crystal structure. The bimetallic complex [Fe(bpca)2][Er(NO3)3(H2O)4](NO3) (where Hbpca = bis(2-pyridilcarbonyl)amine) crystallizes in the triclinic space group P over(1, ̄) exhibiting stacks of [Fe(bpca)2]+ and [Er(NO3)3(H2O)4] entities connected by hydrogen bonds. The [Er(NO3)3(H2O)4] units are connected by hydrogen bonds established between coordinated aqua and nitrate ligands. Static and dynamic magnetic properties are reported. The complex exhibits the magnetization lag in ac magnetic field of 10-1400 Hz, above 1.8 K, under a static magnetic field. The ab initio calculations, including ligand field and spin orbit effects illuminated the anisotropy properties of the lanthanide ions in the complex, revealing the orientation and extension of the lobes corresponding to the easy magnetization axes.

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KW - Magnetic anisotropy

KW - Magnetic properties

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