TY - JOUR
T1 - The first x-ray analysis of a phospha[3]radialene
AU - Miyahara, Ikuko
AU - Hayashi, Atsuhiro
AU - Hirotsu, Ken
AU - Yoshifuji, Masaaki
AU - Yoshimura, Hideki
AU - Toyota, Kozo
N1 - Funding Information:
methylene)-2-(2,4,6-tri-t-butylphenyl)-1,2-thiaphos-and Culture, Japanese Government (No. phirane2 -sulphide( 8).I 3 The bond angles,C (2)-03233105 and No. 02403008) and the Asahi Glass P-C(3) [115.8(l)“]a nd P-C(3)-C(4) [129.3(l)“], Research Fund from the Asahi Glass Foundation. The are abnormally opened with concomitant con-authors also thank Tosoh Akzo Co, Ltd for donation of traction of C(l)--P-C(3) [106.7(l)“] and organolithium reagentst hroughout this work. P-C(3)-C(8) [109.3(2)“]T. his reflectst he large
PY - 1992
Y1 - 1992
N2 - 2-(Dichloromethylene)-3-(diphenylmethylene)-1-(2,4,6-tri-t-butylphenyl)- 1-phosphirane, prepared from 4,4-diphenyl-1-(2,4,6-tri-t-butylphenyl)-1-phospha-1,2,3-butatriene and dichlorocarbene, was analysed by X-ray crystallography for the first time as an example of phospha[3]radialene.
AB - 2-(Dichloromethylene)-3-(diphenylmethylene)-1-(2,4,6-tri-t-butylphenyl)- 1-phosphirane, prepared from 4,4-diphenyl-1-(2,4,6-tri-t-butylphenyl)-1-phospha-1,2,3-butatriene and dichlorocarbene, was analysed by X-ray crystallography for the first time as an example of phospha[3]radialene.
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U2 - 10.1016/S0277-5387(00)83187-3
DO - 10.1016/S0277-5387(00)83187-3
M3 - Article
AN - SCOPUS:0006589762
SN - 0277-5387
VL - 11
SP - 385
EP - 387
JO - Polyhedron
JF - Polyhedron
IS - 3
ER -