The first total synthesis of gravicycle

Katsuaki Ueda; Itaru Sato; Masahiro Hirama

doi:10.1246/cl.2012.87

The first total synthesis of gravicycle

Katsuaki Ueda, Itaru Sato, Masahiro Hirama

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The total synthesis of gravicycle, isolated from Grevillea robusta, has been achieved for the first time. The key step of our synthetic process is the efficient assembly of a highly functionalized biaryl ether via the copper-catalyzed O-arylation of suitably protected pyrogallol-5-carboxylate, using triarylbismuth( V) diacetate.

Original language	English
Pages (from-to)	87-89
Number of pages	3
Journal	Chemistry Letters
Volume	41
Issue number	1
DOIs	https://doi.org/10.1246/cl.2012.87
Publication status	Published - 2012

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2012.87

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abstract = "The total synthesis of gravicycle, isolated from Grevillea robusta, has been achieved for the first time. The key step of our synthetic process is the efficient assembly of a highly functionalized biaryl ether via the copper-catalyzed O-arylation of suitably protected pyrogallol-5-carboxylate, using triarylbismuth( V) diacetate.",

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The first total synthesis of gravicycle

Abstract

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