Abstract
The total synthesis of gravicycle, isolated from Grevillea robusta, has been achieved for the first time. The key step of our synthetic process is the efficient assembly of a highly functionalized biaryl ether via the copper-catalyzed O-arylation of suitably protected pyrogallol-5-carboxylate, using triarylbismuth( V) diacetate.
Original language | English |
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Pages (from-to) | 87-89 |
Number of pages | 3 |
Journal | Chemistry Letters |
Volume | 41 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2012 |
ASJC Scopus subject areas
- Chemistry(all)