The first supramolecular photosensitization of enantiodifferentiating bimolecular reaction: anti-Markovnikov photoaddition of methanol to 1,1-diphenylpropene sensitized by modified β-cyclodextrin

Gaku Fukuhara, Tadashi Mori, Takehiko Wada, Yoshihisa Inoue

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Enantiodifferentiating polar photoaddition of methanol to 1,1-diphenylpropene included and sensitized by cyanonaphthalene-modified β-cyclodextrin was examined for the first time to give optically active anti-Markovnikov adduct with accompanying inversion of the chiral sense of the photoproduct by temperature, which is entropic in origin.

Original languageEnglish
Pages (from-to)1712-1714
Number of pages3
JournalChemical Communications
Issue number16
DOIs
Publication statusPublished - 2006
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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