The first separation of an optically active 1,3-diphospha-allene of axial dissymmetry

Masaaki Yoshifuji, Kozo Toyota, Takashi Niitsu, Naoki Inamoto, Yoshio Okamoto, Ryo Aburatani

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Separation of enantiomers of axially dissymmetric 1,3-bis(2,4,6-tri-t- butylphenyl)-1,3-diphospha-allene was successful for the first time by h.p.l.c. with a chiral (+)-poly(triphenylmethyl methacrylate) column and the c.d. spectrum of the optically pure (-)-phospha-allene was recorded; racemization occurred on exposure to light but the rate was very slow in the dark.

Original languageEnglish
Pages (from-to)1550-1551
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number20
DOIs
Publication statusPublished - 1986 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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