TY - JOUR
T1 - The first separation of an optically active 1,3-diphospha-allene of axial dissymmetry
AU - Yoshifuji, Masaaki
AU - Toyota, Kozo
AU - Niitsu, Takashi
AU - Inamoto, Naoki
AU - Okamoto, Yoshio
AU - Aburatani, Ryo
PY - 1986/1/1
Y1 - 1986/1/1
N2 - Separation of enantiomers of axially dissymmetric 1,3-bis(2,4,6-tri-t- butylphenyl)-1,3-diphospha-allene was successful for the first time by h.p.l.c. with a chiral (+)-poly(triphenylmethyl methacrylate) column and the c.d. spectrum of the optically pure (-)-phospha-allene was recorded; racemization occurred on exposure to light but the rate was very slow in the dark.
AB - Separation of enantiomers of axially dissymmetric 1,3-bis(2,4,6-tri-t- butylphenyl)-1,3-diphospha-allene was successful for the first time by h.p.l.c. with a chiral (+)-poly(triphenylmethyl methacrylate) column and the c.d. spectrum of the optically pure (-)-phospha-allene was recorded; racemization occurred on exposure to light but the rate was very slow in the dark.
UR - http://www.scopus.com/inward/record.url?scp=37049090403&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049090403&partnerID=8YFLogxK
U2 - 10.1039/C39860001550
DO - 10.1039/C39860001550
M3 - Article
AN - SCOPUS:37049090403
SP - 1550
EP - 1551
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 20
ER -