The first isolation of 1,3-diaza-2-sila-4-cyclopentene radical cation salt: The x-ray structure and electronic properties

Shintaro Ishida, Tohru Nishinaga, Koichi Komatsu

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The first TPFPB salt of 1,3-diaza-2-sila-4-cyclopentene (DASCP) radical cation was isolated as an orange crystalline solid by one-electron oxidation of the neutral DASCP with Ag(I) ion. The X-ray structural analysis and theoretical studies showed that the silicon atom plays an important role in stabilization of this cationic species.

Original languageEnglish
Pages (from-to)486-487
Number of pages2
JournalChemistry Letters
Volume34
Issue number4
DOIs
Publication statusPublished - 2005 Apr 5
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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