The first high molecular weight poly(N-alkyl-3,6-carbazole)s [2]

Zhong Biao Zhang; Michiya Fujiki; Hong Zhi Tang; Masao Motonaga; Keiichi Torimitsu

doi:10.1021/ma011911b

The first high molecular weight poly(N-alkyl-3,6-carbazole)s [2]

Zhong Biao Zhang, Michiya Fujiki, Hong Zhi Tang, Masao Motonaga, Keiichi Torimitsu

Research output: Contribution to journal › Letter › peer-review

135 Citations (Scopus)

Abstract

The synthesis of the carbazole main chain homopolymers with high molecular weights by applying the reverse addition order of a nickel catalyst based on the Yamamoto coupling method was discussed. The obtained polycarbazoles possess good soubility, film-forming ability, thermal stability and moderately high photoluminescence efficiency. Differential scanning calorimetric (DSC) and thermogravimetric analysis (TGA) were carried out to determine the thermal transition and degradation behavior of the polymers.

Original language	English
Pages (from-to)	1988-1990
Number of pages	3
Journal	Macromolecules
Volume	35
Issue number	6
DOIs	https://doi.org/10.1021/ma011911b
Publication status	Published - 2002 Mar 12
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma011911b

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abstract = "The synthesis of the carbazole main chain homopolymers with high molecular weights by applying the reverse addition order of a nickel catalyst based on the Yamamoto coupling method was discussed. The obtained polycarbazoles possess good soubility, film-forming ability, thermal stability and moderately high photoluminescence efficiency. Differential scanning calorimetric (DSC) and thermogravimetric analysis (TGA) were carried out to determine the thermal transition and degradation behavior of the polymers.",

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T1 - The first high molecular weight poly(N-alkyl-3,6-carbazole)s [2]

AU - Zhang, Zhong Biao

AU - Fujiki, Michiya

AU - Tang, Hong Zhi

AU - Motonaga, Masao

AU - Torimitsu, Keiichi

PY - 2002/3/12

Y1 - 2002/3/12

N2 - The synthesis of the carbazole main chain homopolymers with high molecular weights by applying the reverse addition order of a nickel catalyst based on the Yamamoto coupling method was discussed. The obtained polycarbazoles possess good soubility, film-forming ability, thermal stability and moderately high photoluminescence efficiency. Differential scanning calorimetric (DSC) and thermogravimetric analysis (TGA) were carried out to determine the thermal transition and degradation behavior of the polymers.

AB - The synthesis of the carbazole main chain homopolymers with high molecular weights by applying the reverse addition order of a nickel catalyst based on the Yamamoto coupling method was discussed. The obtained polycarbazoles possess good soubility, film-forming ability, thermal stability and moderately high photoluminescence efficiency. Differential scanning calorimetric (DSC) and thermogravimetric analysis (TGA) were carried out to determine the thermal transition and degradation behavior of the polymers.

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JO - Macromolecules

JF - Macromolecules

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