The first high molecular weight poly(N-alkyl-3,6-carbazole)s [2]

Zhong Biao Zhang, Michiya Fujiki, Hong Zhi Tang, Masao Motonaga, Keiichi Torimitsu

Research output: Contribution to journalLetterpeer-review

135 Citations (Scopus)

Abstract

The synthesis of the carbazole main chain homopolymers with high molecular weights by applying the reverse addition order of a nickel catalyst based on the Yamamoto coupling method was discussed. The obtained polycarbazoles possess good soubility, film-forming ability, thermal stability and moderately high photoluminescence efficiency. Differential scanning calorimetric (DSC) and thermogravimetric analysis (TGA) were carried out to determine the thermal transition and degradation behavior of the polymers.

Original languageEnglish
Pages (from-to)1988-1990
Number of pages3
JournalMacromolecules
Volume35
Issue number6
DOIs
Publication statusPublished - 2002 Mar 12
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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