Abstract
The first unequivocal circular dichroism spectra were obtained for organic radical cations, which were prepared from p-(1S,2S,5R)-neomenthyloxyanisole (1) and p-(1S,2S,4S)-isobornyloxyanisole (2) by single electron oxidation with triethyloxonium hexachloroantimonate in dichloromethane. The chiroptical properties of the radical cations 1.+ and 2.+ were discussed in comparison with those of neutral species 1 and 2.
Original language | English |
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Pages (from-to) | 115-118 |
Number of pages | 4 |
Journal | Enantiomer |
Volume | 7 |
Issue number | 2-3 |
DOIs | |
Publication status | Published - 2002 Mar |
Externally published | Yes |
Keywords
- Circular dichroism
- Cotton effect
- Dimethoxybenzene derivatives
- Electron transfer
- Oxidation
- Radical cation
ASJC Scopus subject areas
- Chemistry(all)
- Biochemistry
- Biochemistry, Genetics and Molecular Biology(all)
- Organic Chemistry