The equilibrium between titanium ions and titanium metal in NaCl-KCl equimolar molten salt

Qiuyu Wang; Jianxun Song; Guojing Hu; Xiaobo Zhu; Jungang Hou; Shuqiang Jiao; Hongmin Zhu

doi:10.1007/s11663-013-9853-5

The equilibrium between titanium ions and titanium metal in NaCl-KCl equimolar molten salt

Qiuyu Wang, Jianxun Song, Guojing Hu, Xiaobo Zhu, Jungang Hou, Shuqiang Jiao, Hongmin Zhu

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

The equilibrium between metallic titanium and titanium ions, 3Ti ²⁺ â‡Œ 2Ti³⁺ + Ti, in NaCl-KCl equimolar molten salt was reevaluated. At a fixed temperature and an initial concentration of titanium chloride, the equilibrium was achieved by adding an excess amount of sponge titanium in assistant with bubbling of argon into the molten salt. The significance of this work is that the accurate concentrations of titanium ions have been obtained based on a reliable approach for taking samples. Furthermore, the equilibrium constant K_C = (x _Ti^3+eql)³/(x_Ti ^2+eql)² was calculated through the best-fitting method under the consideration of the TiOCl dissolution. Indeed, the final results have disclosed that the stable value of K_C could be achieved based on all modifications.

Original language	English
Pages (from-to)	906-913
Number of pages	8
Journal	Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
Volume	44
Issue number	4
DOIs	https://doi.org/10.1007/s11663-013-9853-5
Publication status	Published - 2013 Aug 1
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Mechanics of Materials
Metals and Alloys
Materials Chemistry

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The equilibrium between titanium ions and titanium metal in NaCl-KCl equimolar molten salt. / Wang, Qiuyu; Song, Jianxun; Hu, Guojing; Zhu, Xiaobo; Hou, Jungang; Jiao, Shuqiang; Zhu, Hongmin.

In: Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, Vol. 44, No. 4, 01.08.2013, p. 906-913.

Research output: Contribution to journal › Article › peer-review

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abstract = "The equilibrium between metallic titanium and titanium ions, 3Ti 2+ {\^a}‡{\OE} 2Ti3+ + Ti, in NaCl-KCl equimolar molten salt was reevaluated. At a fixed temperature and an initial concentration of titanium chloride, the equilibrium was achieved by adding an excess amount of sponge titanium in assistant with bubbling of argon into the molten salt. The significance of this work is that the accurate concentrations of titanium ions have been obtained based on a reliable approach for taking samples. Furthermore, the equilibrium constant KC = (x Ti3+eql)3/(xTi 2+eql)2 was calculated through the best-fitting method under the consideration of the TiOCl dissolution. Indeed, the final results have disclosed that the stable value of KC could be achieved based on all modifications.",

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AU - Wang, Qiuyu

AU - Song, Jianxun

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AU - Hou, Jungang

AU - Jiao, Shuqiang

AU - Zhu, Hongmin

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