The effects of temperature and inorganic salts on the aqueous solubility of selected chlorobenzenes

Sylwia Oleszek-Kudlak, Etsuro Shibata, Takashi Nakamura

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The experimental results reported in this paper are the first in a wider research program aiming to test, in a laboratory, the behavior of selected hydrophobic compounds in an aqueous system. The generator column method was used to determine the solubility in water of biphenyl, 1,2-dichlorobenzene (1,2-DCBz), and hexachlorobenzene (HxCBz) at 25 °C. The solubilities of 1,2-DCBz and HxCBz were measured at temperatures ranging from 15 to 55 °C, and the enthalpies of solutions were derived from van't Hoff plots. The effects of three electrolytes on the solubility of HxCBz were determined at 25 °C, and their newly obtained Setschenow constants are reported.

Original languageEnglish
Pages (from-to)570-575
Number of pages6
JournalJournal of Chemical and Engineering Data
Volume49
Issue number3
DOIs
Publication statusPublished - 2004 May 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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