The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines

Kenso Soai; Itaru Sato

doi:10.1016/j.crci.2003.06.002

The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines

Kenso Soai, Itaru Sato

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Short survey › peer-review

19 Citations (Scopus)

Abstract

Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.

Original language	English
Pages (from-to)	1097-1104
Number of pages	8
Journal	Comptes Rendus Chimie
Volume	6
Issue number	8-10
DOIs	https://doi.org/10.1016/j.crci.2003.06.002
Publication status	Published - 2003 Aug

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

Access to Document

10.1016/j.crci.2003.06.002

Fingerprint Dive into the research topics of 'The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines'. Together they form a unique fingerprint.

Cite this

@article{5cf390a292fb44108c12a1469bb0b097,

title = "The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines",

abstract = "Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.",

author = "Kenso Soai and Itaru Sato",

year = "2003",

month = aug,

doi = "10.1016/j.crci.2003.06.002",

language = "English",

volume = "6",

pages = "1097--1104",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

publisher = "Elsevier Masson",

number = "8-10",

}

TY - JOUR

T1 - The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines

AU - Soai, Kenso

AU - Sato, Itaru

PY - 2003/8

Y1 - 2003/8

N2 - Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.

AB - Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.

UR - http://www.scopus.com/inward/record.url?scp=0242656282&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0242656282&partnerID=8YFLogxK

U2 - 10.1016/j.crci.2003.06.002

DO - 10.1016/j.crci.2003.06.002

M3 - Short survey

AN - SCOPUS:0242656282

VL - 6

SP - 1097

EP - 1104

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

SN - 1631-0748

IS - 8-10

ER -