The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines

Kenso Soai; Itaru Sato

doi:10.1016/j.crci.2003.06.002

The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines

Kenso Soai, Itaru Sato

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Short survey › peer-review

19 Citations (Scopus)

Abstract

Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.

Original language	English
Pages (from-to)	1097-1104
Number of pages	8
Journal	Comptes Rendus Chimie
Volume	6
Issue number	8-10
DOIs	https://doi.org/10.1016/j.crci.2003.06.002
Publication status	Published - 2003 Aug

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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abstract = "Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.",

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AU - Sato, Itaru

PY - 2003/8

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AB - Chiral dendrimers bearing β-amino alcohols on their hyperbranched chain-ends serve as highly enantioselective catalysts and ligands in the enantioselective addition of dialkylzincs to aldehydes with up to 93% ee, and in the enantioselective addition of dialkylzincs to N -diphenylphosphinylimines with up to 94% ee, respectively.

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JO - Comptes Rendus Chimie

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ER -

The design of chiral dendritic catalysts and ligands bearing chiral sites at the periphery for the highly enantioselective addition of dialkylzincs to aldehydes and N-diphenylphosphinylimines

Abstract

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