The catalyzed hydrogen sorption mechanism in alkali alanates

Züleyha Özlem Kocabas Atakli, Elsa Callini, Shunsuke Kato, Philippe Mauron, Shin Ichi Orimo, Andreas Züttel

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The hydrogen sorption pathways of alkali alanates were analyzed and a mechanism for the catalytic hydrogen sorption was developed. Gibbs free energy values of selected intermediate steps were calculated based on experimentally determined thermodynamic data (enthalpies and entropies) of individual hydrides: MAlH4, M3AlH6, and MH. The values of the activation energies, based on the intermediates M+, H-, MH, and AlH3, were obtained. The mechanism of the catalytic activity of Ti is finally clarified: we present an atomistic model, where MAlH4 desorbs hydrogen through the intermediates M+, H-, MH, and AlH3 to the hexahydride M3AlH6 and finally the elemental hydride MH. The catalyst acts as a bridge to transfer M+ and H- from MAlH4- to the neighboring AlH4-, forming AlH63- and finally isolated MH, leaving AlH3 behind, which spontaneously desorbs hydrogen to give Al and 1.5H2. The proposed mechanism is symmetric in the direction of hydrogen desorption as well as readsorption processes.

Original languageEnglish
Pages (from-to)20932-20940
Number of pages9
JournalPhysical Chemistry Chemical Physics
Volume17
Issue number32
DOIs
Publication statusPublished - 2015 Aug 28

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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