The asymmetric power of chiral ligands determined by competitive asymmetric autocatalysis

François Lutz; Itaru Sato; Kenso Soai

doi:10.1021/ol049559k

The asymmetric power of chiral ligands determined by competitive asymmetric autocatalysis

François Lutz, Itaru Sato, Kenso Soai

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Asymmetric autocatalytic reactions were initiated by using two competing chiral ligands bearing opposite configurations. The absolute configuration of the resulting highly enantioenriched product reflects the different efficiencies of the two catalysts. Thus, our method provides a simple and efficient way to compare the asymmetric power of chiral ligands for enantioselective catalysis both qualitatively and quantitatively.

Original language	English
Pages (from-to)	1613-1616
Number of pages	4
Journal	Organic letters
Volume	6
Issue number	10
DOIs	https://doi.org/10.1021/ol049559k
Publication status	Published - 2004 May 13

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "Asymmetric autocatalytic reactions were initiated by using two competing chiral ligands bearing opposite configurations. The absolute configuration of the resulting highly enantioenriched product reflects the different efficiencies of the two catalysts. Thus, our method provides a simple and efficient way to compare the asymmetric power of chiral ligands for enantioselective catalysis both qualitatively and quantitatively.",

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AB - Asymmetric autocatalytic reactions were initiated by using two competing chiral ligands bearing opposite configurations. The absolute configuration of the resulting highly enantioenriched product reflects the different efficiencies of the two catalysts. Thus, our method provides a simple and efficient way to compare the asymmetric power of chiral ligands for enantioselective catalysis both qualitatively and quantitatively.

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The asymmetric power of chiral ligands determined by competitive asymmetric autocatalysis

Abstract

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