The Asymmetric Metalation of Chiral Arylaldehyde Acetal Chromium Tricarbonyl Complexes

Yoshinori Kondo; James R. Green; Jianwei Ho

doi:10.1021/jo00026a005

The Asymmetric Metalation of Chiral Arylaldehyde Acetal Chromium Tricarbonyl Complexes

Yoshinori Kondo, James R. Green, Jianwei Ho

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.

Original language	English
Pages (from-to)	7199-7201
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	56
Issue number	26
DOIs	https://doi.org/10.1021/jo00026a005
Publication status	Published - 1991 Dec 1

ASJC Scopus subject areas

Organic Chemistry

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title = "The Asymmetric Metalation of Chiral Arylaldehyde Acetal Chromium Tricarbonyl Complexes",

abstract = "The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.",

author = "Yoshinori Kondo and Green, {James R.} and Jianwei Ho",

year = "1991",

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doi = "10.1021/jo00026a005",

language = "English",

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journal = "Journal of Organic Chemistry",

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T1 - The Asymmetric Metalation of Chiral Arylaldehyde Acetal Chromium Tricarbonyl Complexes

AU - Kondo, Yoshinori

AU - Green, James R.

AU - Ho, Jianwei

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.

AB - The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.

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U2 - 10.1021/jo00026a005

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 26

ER -

The Asymmetric Metalation of Chiral Arylaldehyde Acetal Chromium Tricarbonyl Complexes

Abstract

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