The Asymmetric Metalation of Chiral Arylaldehyde Acetal Chromium Tricarbonyl Complexes

Yoshinori Kondo, James R. Green, Jianwei Ho

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The chiral chromium tricarbonyl complex of benzaldehyde acetal 2, derived from (+)-diethyl tartrate, can be metalated by n-BuLi and subsequently functionalized by various electrophiles with a minimum of 86% de.

Original languageEnglish
Pages (from-to)7199-7201
Number of pages3
JournalJournal of Organic Chemistry
Volume56
Issue number26
DOIs
Publication statusPublished - 1991 Dec 1

ASJC Scopus subject areas

  • Organic Chemistry

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