Tetrameric ααββ aggregate formation by stereoisomeric bidomain helicene oligomers

Wataru Ichinose, Jun Ito, Masahiko Yamaguchi

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

How to aggregate your domains: A method of forming tetrameric aggregates with an ααββ structure has been developed using stereoisomeric bidomain oligomers. Upon mixing the oligomers, a tetrameric ααββ aggregate was obtained by heteroaggregation at the ethynyl domain. The tetrameric aggregate reversibly changed its structure between the dimeric homoaggregates on heating and cooling, whereas gelation by polymerization occurred in toluene.

Original languageEnglish
Pages (from-to)5290-5294
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number20
DOIs
Publication statusPublished - 2013 May 10

Keywords

  • gels
  • helical structures
  • heteroaggregate
  • structure change
  • tetrameric

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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