Abstract
How to aggregate your domains: A method of forming tetrameric aggregates with an ααββ structure has been developed using stereoisomeric bidomain oligomers. Upon mixing the oligomers, a tetrameric ααββ aggregate was obtained by heteroaggregation at the ethynyl domain. The tetrameric aggregate reversibly changed its structure between the dimeric homoaggregates on heating and cooling, whereas gelation by polymerization occurred in toluene.
| Original language | English |
|---|---|
| Pages (from-to) | 5290-5294 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - 2013 May 10 |
Keywords
- gels
- helical structures
- heteroaggregate
- structure change
- tetrameric
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Ichinose, W., Ito, J., & Yamaguchi, M. (2013). Tetrameric ααββ aggregate formation by stereoisomeric bidomain helicene oligomers. Angewandte Chemie - International Edition, 52(20), 5290-5294. https://doi.org/10.1002/anie.201301463