Tetrakis(trimethylsilyl)ethylene and related compounds, crowded olefins

Hideki Sakurai; Yasuhiro Nakadaira; Mitsuo Kira; Hiromi Tobita

doi:10.1016/S0040-4039(00)77412-0

Tetrakis(trimethylsilyl)ethylene and related compounds, crowded olefins

Hideki Sakurai, Yasuhiro Nakadaira, Mitsuo Kira, Hiromi Tobita

Institute for Excellence in Higher Education (IEHE) (organization affiliation only)

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Tetrakis(trimethylsilyl)ethylene (1), tris(trimethylsilyl) (dimethylsilyl)ethylene and 1,2-bis(trimethylsilyl)-1,2-bis(dimethylsilyl)ethylene have been prepared and spectral properties are described. ESR spectra of anion and cation radicals of 1 are also recorded, indicating a nonplanar twisted structure for 1. These crowded olefins show interesting reversible thermochromism.

Original language	English
Pages (from-to)	3077-3080
Number of pages	4
Journal	Tetrahedron Letters
Volume	21
Issue number	32
DOIs	https://doi.org/10.1016/S0040-4039(00)77412-0
Publication status	Published - 1980

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "Tetrakis(trimethylsilyl)ethylene (1), tris(trimethylsilyl) (dimethylsilyl)ethylene and 1,2-bis(trimethylsilyl)-1,2-bis(dimethylsilyl)ethylene have been prepared and spectral properties are described. ESR spectra of anion and cation radicals of 1 are also recorded, indicating a nonplanar twisted structure for 1. These crowded olefins show interesting reversible thermochromism.",

author = "Hideki Sakurai and Yasuhiro Nakadaira and Mitsuo Kira and Hiromi Tobita",

year = "1980",

doi = "10.1016/S0040-4039(00)77412-0",

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journal = "Tetrahedron Letters",

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T1 - Tetrakis(trimethylsilyl)ethylene and related compounds, crowded olefins

AU - Sakurai, Hideki

AU - Nakadaira, Yasuhiro

AU - Kira, Mitsuo

AU - Tobita, Hiromi

PY - 1980

Y1 - 1980

N2 - Tetrakis(trimethylsilyl)ethylene (1), tris(trimethylsilyl) (dimethylsilyl)ethylene and 1,2-bis(trimethylsilyl)-1,2-bis(dimethylsilyl)ethylene have been prepared and spectral properties are described. ESR spectra of anion and cation radicals of 1 are also recorded, indicating a nonplanar twisted structure for 1. These crowded olefins show interesting reversible thermochromism.

AB - Tetrakis(trimethylsilyl)ethylene (1), tris(trimethylsilyl) (dimethylsilyl)ethylene and 1,2-bis(trimethylsilyl)-1,2-bis(dimethylsilyl)ethylene have been prepared and spectral properties are described. ESR spectra of anion and cation radicals of 1 are also recorded, indicating a nonplanar twisted structure for 1. These crowded olefins show interesting reversible thermochromism.

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U2 - 10.1016/S0040-4039(00)77412-0

DO - 10.1016/S0040-4039(00)77412-0

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

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ER -

Tetrakis(trimethylsilyl)ethylene and related compounds, crowded olefins

Abstract

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