TY - JOUR
T1 - Tether-linked [60]fullerene-donor dyads
AU - Zheng, Jian Yu
AU - Noguchi, Shuichi
AU - Miyauchi, Kenjo
AU - Hamada, Masahiro
AU - Kinbara, Kazushi
AU - Saigo, Kazuhiko
PY - 2001/11
Y1 - 2001/11
N2 - The bis-cyclopropanation of fullerene with tether-linked bis-malonates was used to synthesize fullerene bis-adducts having a π-electron rich aromatic ring as a donor in a face-to-face arrangement. The reactions of 2b-e with fullerene were performed in the presence of 1,8-diazabicyclo[5,4,0]undec-7-ene (DBU) and iodine. Results showed that a photoinduced intramolecular electron transfer caused quenching of its fluorescence in a polar solvent.
AB - The bis-cyclopropanation of fullerene with tether-linked bis-malonates was used to synthesize fullerene bis-adducts having a π-electron rich aromatic ring as a donor in a face-to-face arrangement. The reactions of 2b-e with fullerene were performed in the presence of 1,8-diazabicyclo[5,4,0]undec-7-ene (DBU) and iodine. Results showed that a photoinduced intramolecular electron transfer caused quenching of its fluorescence in a polar solvent.
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U2 - 10.1081/FST-100107149
DO - 10.1081/FST-100107149
M3 - Article
AN - SCOPUS:0035504068
VL - 9
SP - 467
EP - 475
JO - Fullerenes Nanotubes and Carbon Nanostructures
JF - Fullerenes Nanotubes and Carbon Nanostructures
SN - 1536-383X
IS - 4
ER -