Tether-linked [60]fullerene-donor dyads

Jian Yu Zheng, Shuichi Noguchi, Kenjo Miyauchi, Masahiro Hamada, Kazushi Kinbara, Kazuhiko Saigo

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The bis-cyclopropanation of fullerene with tether-linked bis-malonates was used to synthesize fullerene bis-adducts having a π-electron rich aromatic ring as a donor in a face-to-face arrangement. The reactions of 2b-e with fullerene were performed in the presence of 1,8-diazabicyclo[5,4,0]undec-7-ene (DBU) and iodine. Results showed that a photoinduced intramolecular electron transfer caused quenching of its fluorescence in a polar solvent.

Original languageEnglish
Pages (from-to)467-475
Number of pages9
JournalFullerene Science and Technology
Volume9
Issue number4
DOIs
Publication statusPublished - 2001 Nov

ASJC Scopus subject areas

  • Chemical Engineering(all)

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