Ternary and quaternary wurtzite-type oxide semiconductors: New materials and their properties

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

β-NaFeO2 structure is an orthorhombic wurtzite-derived structure, of which the structural relationship with wurtzite structure is similar to that of the chalcopyrite sturcture with zincblende structure. β-LiGaO2, β-AgGaO2 and β-AgAlO2 are known as materials possessing the β-NaFeO2 structure; however, studies on the wurtzite-derived ternary oxide semiconductors are quite limited. Recently, we demonstrated the band gap engineering of zinc oxide by alloying with wurtzite-type β-AgGaO2, and the band gap of ZnO was reduced to 2.55 eV by this alloying. Very recently, a new wurtzite-type ternary compound, β-CuGaO2, was found out. Its energy band gap was 1.47 eV, and it exhibited p-type conduction. The first principle calculation indicated that β-CuGaO2 is a direct semiconductor; therefore it is suitable to use in optoelectronic devices. Taking the 1.47 eV of the band gap and p-type electronic conduction into account, β- CuGaO2 is a promising material for the thin film solar cell absorber. These new ternary oxide semiconductors possessing wurtzite-derived structure expanded the energy region that the oxide semiconductors cover into visible and near-infrared region.

Original languageEnglish
Title of host publicationOxide-Based Materials and Devices VI
EditorsFerechteh H. Teherani, David C. Look, David J. Rogers
PublisherSPIE
ISBN (Electronic)9781628414547
DOIs
Publication statusPublished - 2015 Jan 1
Externally publishedYes
EventOxide-Based Materials and Devices VI - San Francisco, United States
Duration: 2015 Feb 82015 Feb 11

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume9364
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Other

OtherOxide-Based Materials and Devices VI
CountryUnited States
CitySan Francisco
Period15/2/815/2/11

Keywords

  • I-III-VI<inf>2</inf> semiconductors
  • Oxide semiconductor
  • Wurtzite structure
  • band gap engineering
  • narrow band gap semiconductors
  • wide band gap semiconductors
  • zinc oxide

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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  • Cite this

    Omata, T. (2015). Ternary and quaternary wurtzite-type oxide semiconductors: New materials and their properties. In F. H. Teherani, D. C. Look, & D. J. Rogers (Eds.), Oxide-Based Materials and Devices VI [93641L] (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 9364). SPIE. https://doi.org/10.1117/12.2175570