Terahertz vibrational spectra of metallocene

Jun ichi Nishizawa, Takenori Tanno, Tadao Tanabe, Ken Suto

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The terahertz transmission spectra of crystalline metallocenes and decamethyl metallocene were clearly measured in the range of 0.7-6.2 THz by a recently developed GaP Raman terahertz spectrometer. The low-frequency mode of ring-metal-ring bending and CH3 out-of-plane oscillation were observed, and the force constants of bending were estimated from the absorption frequencies based on a three-body model.

Original languageEnglish
Pages (from-to)2479-2482
Number of pages4
JournalJournal of Organometallic Chemistry
Volume691
Issue number11
DOIs
Publication statusPublished - 2006 May 15

Keywords

  • Deuteration
  • Metallocene
  • Spectroscopy
  • Terahertz wave
  • Vibrational mode

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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