Abstract
(Chemical Equation Presented) The novel catalytic method for the oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones is described. TEMPO/NaIO4-SiO 2 causes facile and efficient oxidative rearrangement of various acyclic substrates as well as medium-sized and macrocyclic substrates.
Original language | English |
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Pages (from-to) | 4715-4718 |
Number of pages | 4 |
Journal | Organic letters |
Volume | 10 |
Issue number | 21 |
DOIs | |
Publication status | Published - 2008 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry