TEMPO/NaIO4-SiO2: A catalytic oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones

Masatoshi Shibuya, Masaki Tomizawa, Yoshiharu Iwabuchi

Research output: Contribution to journalArticlepeer-review

37 Citations (Scopus)

Abstract

(Chemical Equation Presented) The novel catalytic method for the oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones is described. TEMPO/NaIO4-SiO 2 causes facile and efficient oxidative rearrangement of various acyclic substrates as well as medium-sized and macrocyclic substrates.

Original languageEnglish
Pages (from-to)4715-4718
Number of pages4
JournalOrganic letters
Volume10
Issue number21
DOIs
Publication statusPublished - 2008 Dec 1

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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