Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex

O. Lintang Hendrik; Kinbara Kazushi; Takuzo Aida

doi:10.4028/www.scientific.net/AMR.364.55

Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex

O. Lintang Hendrik, Kinbara Kazushi, Takuzo Aida

Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

1 Citation (Scopus)

Abstract

Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au₃Pz₃] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylorthosilicate (TBOS) to [Au₃Pz₃] in an acidic aqueous alcohol solution from 60:1 to 20:1, highly ordered phosphorescent nanocomposites can be fabricated with hexagonal [Au ₃Pz₃]/silica_hex and lamellar [Au ₃Pz₃]/silica_lam silicates.

Original language	English
Title of host publication	Nanomaterials
Subtitle of host publication	Synthesis and Characterization
Pages	55-59
Number of pages	5
DOIs	https://doi.org/10.4028/www.scientific.net/AMR.364.55
Publication status	Published - 2012 Jan 1
Event	2011 International Conference on Nanomaterials, Synthesis and Characterization, ICNSC2011 - Selangor, Malaysia Duration: 2011 Jul 4 → 2011 Jul 5

Publication series

Name	Advanced Materials Research
Volume	364
ISSN (Print)	1022-6680

Other

Other	2011 International Conference on Nanomaterials, Synthesis and Characterization, ICNSC2011
Country	Malaysia
City	Selangor
Period	11/7/4 → 11/7/5

Keywords

Hexagonal
Mesoporous silica
Nanocomposites
Sol-gel synthesis
Template

ASJC Scopus subject areas

Engineering(all)

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Hendrik, O. L., Kazushi, K., & Aida, T. (2012). Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex. In Nanomaterials: Synthesis and Characterization (pp. 55-59). (Advanced Materials Research; Vol. 364). https://doi.org/10.4028/www.scientific.net/AMR.364.55

Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex. / Hendrik, O. Lintang; Kazushi, Kinbara; Aida, Takuzo.

Nanomaterials: Synthesis and Characterization. 2012. p. 55-59 (Advanced Materials Research; Vol. 364).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Hendrik, OL, Kazushi, K & Aida, T 2012, Template sol-gel synthesis of phosphorescent mesoporous silica film nanocomposites using an amphiphilic gold(i) pyrazolate complex. in Nanomaterials: Synthesis and Characterization. Advanced Materials Research, vol. 364, pp. 55-59, 2011 International Conference on Nanomaterials, Synthesis and Characterization, ICNSC2011, Selangor, Malaysia, 11/7/4. https://doi.org/10.4028/www.scientific.net/AMR.364.55

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abstract = "Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au3Pz3] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylorthosilicate (TBOS) to [Au3Pz3] in an acidic aqueous alcohol solution from 60:1 to 20:1, highly ordered phosphorescent nanocomposites can be fabricated with hexagonal [Au 3Pz3]/silicahex and lamellar [Au 3Pz3]/silicalam silicates.",

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