Abstract
We present a strategy for creating coordination frameworks exhibiting proton conduction with thermal stability. The coordination framework, where template cations link 1-D chains via hydrogen bonds, has dynamic hydrogen bond networks where protons move without water support. Solid-state NMR and X-ray studies visualized the proton hopping mechanism, and revealed that the templates provide the bridging of the 1-D chains to attain proton conduction. The templates also enable the proton conductive networks to be maintained at 190 °C through multiple interactions between the templates and the 1-D chains.
Original language | English |
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Pages (from-to) | 10404-10409 |
Number of pages | 6 |
Journal | Journal of Materials Chemistry A |
Volume | 2 |
Issue number | 27 |
DOIs | |
Publication status | Published - 2014 Jul 21 |
ASJC Scopus subject areas
- Chemistry(all)
- Renewable Energy, Sustainability and the Environment
- Materials Science(all)