Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts

Kazumasa Ueda; Toyonari Sugimoto; Toshiharu Tada; Kei Ichiro Nishimura; Satoshi Endo; Naoki Toyota; Masakado Kohama; Koji Yamamoto; Toshiyuki Yamaguchi; Yusaku Suenaga; Megumu Munakata; Nobuko Kanehisa; Yoshiyuki Shibamoto; Yasushi Kai; Nobuyoshi Hosoito

doi:10.1080/10587259708032330

Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts

Kazumasa Ueda, Toyonari Sugimoto, Toshiharu Tada, Kei Ichiro Nishimura, Satoshi Endo, Naoki Toyota, Masakado Kohama, Koji Yamamoto, Toshiyuki Yamaguchi, Yusaku Suenaga, Megumu Munakata, Nobuko Kanehisa, Yoshiyuki Shibamoto, Yasushi Kai, Nobuyoshi Hosoito

SCI - Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of a plate crystal of ((PMe₄⁺·TCNQF₄ ^-.)·1/2TCNQF₄) was analyzed and very similar to that of the corresponding NMe₄⁺ salt. However, significant difference was recognized between the two crystals in the structures of TCNQF₄ and TCNQF₄^-. molecules, and especially in the contacts between the two TCNQF₄^-. molecules in dimerization and between the TCNQF₄ and TCNQF₄^-. molecules. The change in both molecular structure and contact as above was also observed at a lowering temperature. The magnitude in change was larger in the NMe₄⁺ salt than in the PMe₄⁺ salt. However, the change exerted no special influence on the elctrical conducting and magnetic properties.

Original language	English
Pages (from-to)	323-333
Number of pages	11
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	296
DOIs	https://doi.org/10.1080/10587259708032330
Publication status	Published - 1997

ASJC Scopus subject areas

Condensed Matter Physics

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10.1080/10587259708032330

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Ueda, K., Sugimoto, T., Tada, T., Nishimura, K. I., Endo, S., Toyota, N., Kohama, M., Yamamoto, K., Yamaguchi, T., Suenaga, Y., Munakata, M., Kanehisa, N., Shibamoto, Y., Kai, Y., & Hosoito, N. (1997). Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 296, 323-333. https://doi.org/10.1080/10587259708032330

Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts. / Ueda, Kazumasa; Sugimoto, Toyonari; Tada, Toshiharu; Nishimura, Kei Ichiro; Endo, Satoshi; Toyota, Naoki; Kohama, Masakado; Yamamoto, Koji; Yamaguchi, Toshiyuki; Suenaga, Yusaku; Munakata, Megumu; Kanehisa, Nobuko; Shibamoto, Yoshiyuki; Kai, Yasushi; Hosoito, Nobuyoshi.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 296, 1997, p. 323-333.

Research output: Contribution to journal › Article › peer-review

Ueda, K, Sugimoto, T, Tada, T, Nishimura, KI, Endo, S, Toyota, N, Kohama, M, Yamamoto, K, Yamaguchi, T, Suenaga, Y, Munakata, M, Kanehisa, N, Shibamoto, Y, Kai, Y & Hosoito, N 1997, 'Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 296, pp. 323-333. https://doi.org/10.1080/10587259708032330

Ueda K, Sugimoto T, Tada T, Nishimura KI, Endo S, Toyota N et al. Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 1997;296:323-333. https://doi.org/10.1080/10587259708032330

Ueda, Kazumasa ; Sugimoto, Toyonari ; Tada, Toshiharu ; Nishimura, Kei Ichiro ; Endo, Satoshi ; Toyota, Naoki ; Kohama, Masakado ; Yamamoto, Koji ; Yamaguchi, Toshiyuki ; Suenaga, Yusaku ; Munakata, Megumu ; Kanehisa, Nobuko ; Shibamoto, Yoshiyuki ; Kai, Yasushi ; Hosoito, Nobuyoshi. / Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts. In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 1997 ; Vol. 296. pp. 323-333.

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title = "Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts",

abstract = "The structure of a plate crystal of ((PMe4+·TCNQF4 -.)·1/2TCNQF4) was analyzed and very similar to that of the corresponding NMe4+ salt. However, significant difference was recognized between the two crystals in the structures of TCNQF4 and TCNQF4-. molecules, and especially in the contacts between the two TCNQF4-. molecules in dimerization and between the TCNQF4 and TCNQF4-. molecules. The change in both molecular structure and contact as above was also observed at a lowering temperature. The magnitude in change was larger in the NMe4+ salt than in the PMe4+ salt. However, the change exerted no special influence on the elctrical conducting and magnetic properties.",

author = "Kazumasa Ueda and Toyonari Sugimoto and Toshiharu Tada and Nishimura, {Kei Ichiro} and Satoshi Endo and Naoki Toyota and Masakado Kohama and Koji Yamamoto and Toshiyuki Yamaguchi and Yusaku Suenaga and Megumu Munakata and Nobuko Kanehisa and Yoshiyuki Shibamoto and Yasushi Kai and Nobuyoshi Hosoito",

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T1 - Temperature dependence of crystal structures, and electrical conducting and magnetic properties in plate crystals of 1:2 tetrafluorotetracyanoquinodimethane/ tetrafluorotetracyanoquinodimethanide mixed tetramethyl-ammonium and -phosphonium salts

AU - Ueda, Kazumasa

AU - Sugimoto, Toyonari

AU - Tada, Toshiharu

AU - Nishimura, Kei Ichiro

AU - Endo, Satoshi

AU - Toyota, Naoki

AU - Kohama, Masakado

AU - Yamamoto, Koji

AU - Yamaguchi, Toshiyuki

AU - Suenaga, Yusaku

AU - Munakata, Megumu

AU - Kanehisa, Nobuko

AU - Shibamoto, Yoshiyuki

AU - Kai, Yasushi

AU - Hosoito, Nobuyoshi

PY - 1997

Y1 - 1997

N2 - The structure of a plate crystal of ((PMe4+·TCNQF4 -.)·1/2TCNQF4) was analyzed and very similar to that of the corresponding NMe4+ salt. However, significant difference was recognized between the two crystals in the structures of TCNQF4 and TCNQF4-. molecules, and especially in the contacts between the two TCNQF4-. molecules in dimerization and between the TCNQF4 and TCNQF4-. molecules. The change in both molecular structure and contact as above was also observed at a lowering temperature. The magnitude in change was larger in the NMe4+ salt than in the PMe4+ salt. However, the change exerted no special influence on the elctrical conducting and magnetic properties.

AB - The structure of a plate crystal of ((PMe4+·TCNQF4 -.)·1/2TCNQF4) was analyzed and very similar to that of the corresponding NMe4+ salt. However, significant difference was recognized between the two crystals in the structures of TCNQF4 and TCNQF4-. molecules, and especially in the contacts between the two TCNQF4-. molecules in dimerization and between the TCNQF4 and TCNQF4-. molecules. The change in both molecular structure and contact as above was also observed at a lowering temperature. The magnitude in change was larger in the NMe4+ salt than in the PMe4+ salt. However, the change exerted no special influence on the elctrical conducting and magnetic properties.

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