Tandem (domino) and two-directional asymmetric catalysis of carbonyl-ene reaction with fluoral: Fluoral-ene approach to modeling of inter-smectic layer interaction of antiferroelectric liquid crystals

Koichi Mikami, Tomoko Yajima, Nasakul Siree, Masahiro Terada, Yoshiichi Suzuki, Yoichi Takanishi, Hideo Takezoe

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

A new type of antiferroelectric liquid crystalline molecule of dimeric TFMHPOBC analogue with tri-methylene tether (3-DmTFMHPOBC) was synthesized based on the binaphthol-titanium complex-catalyzed tandem and two-directional fluoral-ene reaction with vinyl sulfides.

Original languageEnglish
Pages (from-to)1895-1898
Number of pages4
JournalSynlett
Issue number12
DOIs
Publication statusPublished - 1999 Jan 1
Externally publishedYes

Keywords

  • Antiferroelectric liquid crystals
  • Binaphthol-titanium complex
  • Fluoral-ene reaction
  • Vinyl sulfides
  • α-trifluoromethyl carbinols

ASJC Scopus subject areas

  • Organic Chemistry

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