Tailored charge transfer complex based on two-dimensional molecular assemblies

M. Shimomura, S. Aiba, S. Oguma, M. Oguchi, M. Matsute, H. Shimada, R. Kajiwara, H. Emori, K. Yoshiwara, K. Okuyama, T. Miyashita, A. Watanabe, M. Matsuda

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

For tailoring charge transfer (CT) complexes in bilayer membranes, single-chain bilayer-forming amphiphiles, having a hydrophilic viologen head and a hydrophobic aromatic segment, such as an azobenzene or a biphenyl group, were prepared. Bilayer membranes with a titled molecular orientation were formed when the amphiphiles which had five carbon atoms in the spacer methylene chain between the viologen head and the aromatic segment were dissolved in water. A visible absorption band at 460 nm, which was attributed to the CT interaction between the viologen head and the biphenyl segment of the adjacent molecule in the two-dimensional molecular array, was newly observed in the bilayer membrane.

Original languageEnglish
Pages (from-to)33-38
Number of pages6
JournalSupramolecular Science
Volume1
Issue number1
DOIs
Publication statusPublished - 1994 Sep
Externally publishedYes

Keywords

  • bilayer membrane
  • charge transfer complex
  • viologen

ASJC Scopus subject areas

  • Engineering(all)

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