Synthetic Studies toward Ciguatoxin. Stereocontrolled Construction of the KLM Ring Fragment

Makoto Sasaki, Masayuki Inoue, Kazuo Tachibana

Research output: Contribution to journalArticle

66 Citations (Scopus)

Abstract

The first stereoselective synthesis of the KLM ring fragment of ciguatoxin is reported including as a key step 7-endo selective cyclization of epoxy alcohol to construct a fully substituted oxepane ring (12 → 13).

Original languageEnglish
Pages (from-to)715-717
Number of pages3
JournalJournal of Organic Chemistry
Volume59
Issue number4
DOIs
Publication statusPublished - 1994 Feb 1
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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